ChemInform Abstract: 3-Trimethylsilylbicyclo[3.2.1]oct-2-ene in the Synthesis of Functionalized Bicyclo[3.2.1]octane Systems.
نویسندگان
چکیده
منابع مشابه
comparison of catalytic activity of heteropoly compounds in the synthesis of bis(indolyl)alkanes.
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15 صفحه اولsynthesis of 3-aryl-2h-benzo[b]-1,4-oxazines in [omim]bf4 and reduction of organic compounds in methylimidazolium formate
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A dynamic kinetic resolution of β-halo α-keto esters in an asymmetric homoenolate reaction is described. A chiral N-hetereocyclic carbene catalyzes the a(3) → d(3)-umpolung addition of α,β-enals to racemic α-keto esters, forming γ-butyrolactones with three contiguous stereocenters. The addition occurs with high regio-, diastereo-, and enantiocontrol. This methodology constitutes an intermolecul...
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ژورنال
عنوان ژورنال: ChemInform
سال: 2010
ISSN: 0931-7597,1522-2667
DOI: 10.1002/chin.200234088